An XSD file is itself an XML document. Here is a schema for the library example:
<?xml version="1.0" encoding="UTF-8"?>
<xs:schema xmlns:xs="http://www.w3.org/2001/XMLSchema">
<xs:element name="library">
<xs:complexType>
<xs:sequence>
<xs:element name="book" maxOccurs="unbounded">
<xs:complexType>
<xs:sequence>
<xs:element name="title" type="xs:string"/>
<xs:element name="author" type="xs:string"/>
<xs:element name="year" type="xs:gYear"/>
</xs:sequence>
<xs:attribute name="id" type="xs:positiveInteger" use="required"/>
</xs:complexType>
</xs:element>
</xs:sequence>
</xs:complexType>
</xs:element>
</xs:schema>
Validate an XML file against an XSD with xmllint:
xmllint --schema library.xsd --noout library.xml
XSD supports built-in types (xs:string, xs:integer, xs:date, xs:boolean…) and lets you define custom simple types with restrictions such as minimum/maximum values, enumerated values, and regular expression patterns.